Cesar Marquez et.al.: ESI-MS study on the aldol reaction catalyzed by L-proline

Author(s): Cesar Marquez, Juergen O. Metzger

Title: ESI-MS study on the aldol reaction catalyzed by L-proline

Date of Upload: 2006

Article: Chem. Commun., 2006, 1539–1541, Institute of Pure and Applied Chemistry, Carl von Ossietzky University Oldenburg, Carl-von-Ossietzky-Strasse 9–11, 26111 Oldenburg (Germany)

Keywords: Mass spectrometry, Microreactor, Radical reactions, Reactive intermediate, ESI-MS, electrosprayionazation, mass spectrometry, reaction, solution, aldol reaction, i-proline, ESI-MS/MS, catalyzed

Abstract:
The aldol reaction catalyzed by l-proline has been monitored and the accepted mechanism confirmed by intercepting and characterizing, for the first time, all the proposed intermediates by ESI-MS/MS.

URL: http://www.chemie.uni-oldenburg.de/oc/metzger/publikationen/pdf/111.pdf (application/pdf)


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