Jens Griep-Raming et.al.: Investigation of Reactive Intermediates of Chemical Reactions in Solution by Electrospray Ionization Mass Spectrometry: Radical Chain Reactions

Author(s): Jens Griep-Raming, Sven Fuermeier, Thorsten Bruhn, Juergen O. Metzger

Title: Investigation of Reactive Intermediates of Chemical Reactions in Solution by Electrospray Ionization Mass Spectrometry: Radical Chain Reactions

Date of Upload: 2002

Article: Angew. Chem. Int. Ed. 2002, 41, No. 15, Department of Chemistry, University of Oldenburg, Carl-von-Ossietzky-Str. 9-11, 26129 Oldenburg, Germany; Thermo Finnigan MAT GmbH, Barkhausenstrasse 2, 28197Brem en (Germany)

Keywords: carbocations, mass spectrometry, radicals, reactive intermediates, scandium, ESI-MS, electrospray massspectrometry, reactive intermediate, reaction, solution

Abstract:
Auseful tool for the investigation of synthetically important tributyltinmediated radical chain reactions is electrospray ionization mass spectrometry(ESIMS). A microreaction system is coupled online to the ESI source. Transient radicals were detected unambiguously by using MS/MS methods

URL: http://www.chemie.uni-oldenburg.de/oc/metzger/publikationen/pdf/92_engl.pdf (application/pdf)


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