Organische Chemie - Metzger

Publikationen Umweltverträgliche Synthesen / Nachwachsende Rohstoffe

Wichtige Publikationen zum Umweltverträgliche Synthesen / Forschungsschwerpunkt Nachwachsende Rohstoffe:

  • U. Biermann, U. Bornscheuer, M.A.R. Meier, J.O. Metzger, H.J. Schäfer, Fette und Öle als nachwachsende Rohstoffe in der Chemie, Angew. Chem. 2011, 123, 3938 - 3956, fulltext; New developments for the chemical utilization of oils and fats as renewable raw materials, Angew. Chem. Int. Ed. 2011, 50, 3854-387, fulltext
  • U. Biermann, M.A.R. Meier, J.O. Metzger, Cross-metathesis of unsaturated triglycerides with methyl acrylate: synthesis of a dimeric metathesis product, Eur. J. Lipid Sci. Technol. 2011, 113, 39-45, fulltext

  • Ursula Biermann, Jürgen O. Metzger, Michael A. R. Meier, Acyclic Triene Metathesis Oligo- and Polymerization of High Oleic Sun Flower Oil, Macromol. Chem. Phys. 2010, 211, 854-862, fulltext

  • Ursula Biermann, Werner Butte, Ralf Holtgrefe, Willi Feder, and Jürgen O. Metzger, Esters of calendula oil and tung oil as reactive diluents for alkyd resins, Eur. J. Lipid Sci. Technol. 2010, 112, 103-109.

  • Jürgen O. Metzger, Fats and oils as renewable feedstock for chemistry, Eur. J. Lipid Sci. Technol. 2009, 111, 865-876, fulltext

  • Marco Eissen, Volker Walter, Tobias Marks und Jürgen O. Metzger, Kombinatorik bei der Fettumesterung, MNU 2009, 62, 268-270, fulltext

  • Jürgen O. Metzger and Aloys Hüttermann, Sustainable global energy supply based on lignocellulosic biomass from afforestation of degraded areas, Naturwissenschaften 2009, 96, 279-288, fulltext.

  • Ursula Biermann and Jürgen O. Metzger, Synthesis of alkyl-branched fatty acids, Eur. J. Lipid Sci. Technol. 2008, 110, 805-811, fulltext

  • Michael A. R. Meier, Jürgen O. Metzger and Ulrich S. Schubert, "Plant oil renewable resources as green alternatives in polymer science", Chem. Soc. Rev., 2007, 36, 1788-1802, fulltext.

  • U. Biermann, W. Butte, T. Eren, D. Haase, J. O. Metzger, "Diels-Alder reactions with Conjugated Triene Fatty Acid Esters", Eur. J. Org. Chem. 2007, 3859-3862, fulltext

  • Ursula Biermann, Rainer Koch, and Jürgen O. Metzger, "Intramolecular Concerted Insertion of Vinyl Cations into C-H Bonds: Hydroalkylating Cyclization of Alkynes with Alkyl Chloroformates", Angew. Chem. 2006, 118, 3146 -3150, fulltext; Angew. Chem. Int. Ed. 2006, 45, 3076 -3079, fulltext.

  • J. O. Metzger and U. Bornscheuer, "Lipids as renewable resources: current state of chemical and biotechnological conversion and diversification", Appl. Microbiol. Biotechnol. 2006, 71, 13-22, fulltext.

  • Ursula Biermann, Arne Lützen, and Jürgen O. Metzger, "Synthesis of Enantiomerically Pure 2,3,4,6-Tetrasubstituted Tetrahydropyrans by Prins-Type Cyclization of Methyl Ricinoleate and Aldehydes", Eur. J. Org. Chem. 2006, 2631-2637, fulltext.

  • .Ursula Biermann, Rainer Koch und Jürgen O. Metzger, "Intramolekulare konzertierte Insertion von Vinylkationen in C-H-Bindungen: cyclisierende Hydroalkylierung von Alkinen mit Chlorameisensäurealkylestern zu Cyclopentanderivaten", Angew. Chem. 2006, 118, 3146 -3150, fulltext.

  • Ursula Biermann, Rainer Koch and Jürgen O. Metzger, "Intramolecular Concerted Insertion of Vinyl Cations into C-H Bonds: Hydroalkylating Cyclization of Alkynes with Alkyl Chloroformates to Give Cyclopentanes", Angew. Chem. Int. Ed. 2006, 45, 3076 -3079, fulltext.

  • Jürgen O. Metzger, Production of Liquid Hydrocarbons from Biomass, Angew. Chem. 2006, 118, 710 - 713, fulltext; Angew. Chem. Int. Ed. 2006, 45, 696 - 698, fulltext.

  • G. G. Lligadas, J. C. Ronda, M. Galia , U. Biermann, J. O. Metzger, Synthesis and Characterization of Polyurethanes from Epoxidized Methyl Oleate Based Polyether Polyols as Renewable Resources, J. Polym. Sci. A, 2006, 44, 634-645, fulltext.

  • U. Biermann, J. O. Metzger, "Alkylation of Alkenes: Ethylaluminum Sesquichloride Mediated Hydro-Alkyl-Additions with Alkyl Chloroformates and Di- tert-butylpyrocarbonate", J. Am. Chem. Soc. 2004, 126, 10319-10330, fulltext

  • Jürgen O. Metzger, Marco Eissen, "Concepts on the contribution of chemistry to a sustainable development. Renewable raw materials", C. R. Chimie, 2004, 7, 569-581 fulltext

  • U. Biermann, J. O. Metzger, Catalytic C,C-Bond Forming Additions to
    Unsaturated Fatty Compounds, Topics in Catalysis, 2004, 38, 3675-3677, fulltext.

  • Sandra Fürmeier, Maureen M. L. Lau, Marcel S. F. Lie Ken Jie, Arne Lützen, and Jürgen O. Metzger, " Expanding the Field of Phosphorus-Containing Fatty Acid Derivatives: Synthesis of 1,2-Oxaphospholene Derivatives and Alkenyl Phosphonates from α-Keto Allenes", Eur. J. Org. Chem. 2003, 4874-4878, fulltext

  • M. S. F. Lie Ken Jie,M. M. L. Lau, C. N. W. Lam , U. Biermann, J. O. Metzger, Novel halo-oxo-allenic fatty ester derivatives from epoxidized methyl santalbate (methyl trans-11-octadecen-9-ynoate), CHEM. PHYS. LIPIDS, 2003, 125, 93-101, Abstract.

  • Marco Eissen, Stefan Dirks, Jürgen O. Metzger and Konrad Hungerbühler, Mass efficiency as metric for the effectiveness of catalysts, Green Chemistry 2003, G25- G27, fulltext.

  • Sandra Fürmeier and Jürgen O. Metzger , Synthesis of New Heterocyclic Fatty Compounds , Eur. J. Org. Chem., 2003, 885-893, fulltext.

  • Sandra Fürmeier and Jürgen O. Metzger, Fat-derived Aziridines and their N-substituted Derivatives: Biologically Active Compounds based on Renewable Raw Materials, Eur. J. Org. Chem., 2003, 649-659, fulltext.

  • Marco Eissen, Jürgen O. Metzger, Environmental Performance Metrics for Daily Use in Synthetic Chemistry, Chem. Eur. J., 2002, 8, 3580-3585 fulltext.

  • M. Eissen, J. O. Metzger, E. Schmidt, U. Schneidewind, Konzepte zum Beitrag der Chemie zu einer nachhaltigen Entwicklung, Angew. Chem. 2002, 114, 402 - 425, fulltext(de); Angew. Chem. Int. Ed. 2002, 41, 414 - 436, fulltext (engl.).

  • J.O. Metzger, Organic Reactions without Solvents and Fats and Oils as Renewable Raw Materials for the Chemical Industry, Chemosphere 2001, 43, 83-87, fulltext.

  • U. Biermann, A. Lützen, M.S.F. Lie Ken Jie, J.O. Metzger, Regioselective Cationic 1,2- and 1,4-Additions Forming Carbon - Carbon Bonds to Methyl Santalbate, a Conjugated Enyne, Eur. J. Org. Chem. 2000, 3069-3073, fulltext.

  • U. Biermann, W. Friedt, S. Lang, W. Lürs, G. Machmüller, J.O. Metzger, M. Rüsch gen. Klaas, H.J. Schäfer, M.P. Schneider, New Syntheses with Oils and Fats as Renewable Feedstock for the Chemical Industry, Angew. Chem., 2000, 112, 2292-2310, fulltext(de); Angew. Chem. Int. Ed. 2000, 39, 2206-2224, fulltext(engl.).

  • U. Biermann, J.O. Metzger, Friedel-Crafts-Alkylation of Alkenes: Ethylaluminium-sesquichloride Induced Alkylations with Alkyl chloroformates, Angew. Chem., 1999, 111, 3874-3876, fulltext(de); Angew. Chem. Int. Ed. 1999, 38, 3675-3677, fulltext(engl.).

  • J.O. Metzger, S. Fürmeier, New Type of Skipped Oligoaziridines: Synthesis of New Fatty Acid Derivatives Containing Aziridine Functions, Eur. J. Org. Chem. 1999, 661-664, fulltext.

  • J.O. Metzger, Solvent-Free Organic Syntheses, Angew. Chem. 1998, 110, 3145-3148, fulltext(de); Angew. Chem. Int. Ed. 1998, 37, 2975-2978, fulltext(engl.).

  • U. Biermann, S. Fürmeier, J.O. Metzger, Some carbon, nitrogen- and carbon, oxygenbond forming additions to unsaturated fatty compounds, Fett/Lipid 1998, 100, 236-246, fulltext.

  • J.O. Metzger and U. Biermann, Lewis acid induced additions to unsaturated fatty compounds IV: Synthesis of cyclopentenones from Friedel-Crafts acylation products of unsaturated fatty compounds with a ,ß-unsaturated acyl chlorides, Fett/Lipid 1998, 100, 2-6, fulltext.

  • J.O. Metzger, R. Mahler and G. Francke, Radical Additions of Alkyl 2-Haloalkanoates and 2-Haloalkanenitriles to Alkenes Initiated by Electron Transfer from Copper in Solvent-Free Systems, Liebigs Ann./Recueil 1997, 2303-2313, fulltext.

  • J.O. Metzger and U. Biermann, Ethylaluminium Dichloride Induced Reactions of Acetals with Unsaturated Carboxylic Esters: Synthesis of Homoallyl Ethers, Liebigs Ann. 1996, 1851-1854, fulltext.

  • J.O. Metzger and U. Biermann, Aluminiumchloride-Induced Additions of Formaldehyde to Alkenes, Bull. Soc. Chim. Belg., 1994, 103, 393-397, fulltext.

  • J.O. Metzger und U. Biermann, Alkylaluminium Dichloride Induced Friedel-Crafts Acylation of Unsaturated Carboxylic Acids and Alcohols, Liebigs Ann. Chem., 1993, 645-650, fulltext.

  • J.O. Metzger und R. Mahler, Free Radical Cyclization of Petroselinic Acid, Liebigs Ann. Chem., 1993, 203-205, fulltext.

  • J.O. Metzger u. Biermann, Alkylaluminium Chloride Catalyzed Ene Reactions of Formaldehyde with Unsaturated Carboxylic Acids, Esters and Alcohols, Synthesis, 1992, 463, fulltext.

Beiträge in Sammelwerken (Auswahl):

  • U. Biermann, S. Fürmeier, J. O. Metzger, "New chemistry of oils and fats", in "Oleochemical manufacture and applications", Eds. F. D. Gunstone, R. J. Hamilton, Sheffield Academic Press, Sheffield, 2001, fulltext.


  • J.O. Metzger, R. Mahler, G. Francke and A. Hayen, Synthesis of New Oleochemicals; Functionalization of Fatty Compounds using Radical Reactions, in "Recent: Developments in the Synthesis of Fatty Acid Derivatives", G. Knothe, J.T.P. Derksen, Eds., American Oil Chemists Society, Champaign, 1999, p. 80-89, fulltext.


  • U. Biermann and J.O. Metzger, Synthesis of New Oleochemicals: Products of Friedel-Crafts Reactions of Unsaturated Fatty Compounds, ebenda, p. 90-99.


  • J.O. Metzger, U. Biermann, G. Francke und R. Mahler, Bereitstellung neuartiger Fettstoffe, in "Chemische Nutzung heimischer Pflanzenöle";, Abschlußkolloquium des BML-Forschungsverbunds, Landwirtschaftsverlag, Münster, 1998, S. 141-176.


  • J.O. Metzger, U. Biermann, R. Mahler und G. Francke, 5. Symposium "Nachwachsende Rohstoffe - Perspektiven für die Chemie", Köllen Druck + Verlag GmbH, Bonn 1997, S. 191-194.


  • J.O. Metzger, U. Biermann und R. Mahler, Neuartige funktionalisierte und verzweigte Fettstoffe, in H. Eierdanz (Hrsg.) "Perspektiven nachwachsender Rohstoffe in der Chemie", VCH, Weinheim, 1996, S. 255-258.