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Uni
Fakultäten
Fk. V
Chemie
OC - Metzger
Publikationen
Radikalchemie
Publikationen Radikalchemie
Wichtige Publikationen zum Forschungsschwerpunkt Radikalchemie:
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Michael Blumenstein, Matthias Lemmler, Ahlke Hayen, and Jürgen
O. Metzger, Enantioselective Hydrogen Transfer Reactions from Chiral
Binaphthyl Variants of Tin Hydrides to Prochiral Radicals, Tetrahedron
Asym., 2003, 3069-3077, fulltext.
- Jens Griep-Raming, Sven Meyer, Torsten Bruhn, Jürgen O. Metzger,
Investigation of Reactive Intermediates of Chemical Reactions in Solution
by Electrospray Ionization Mass Spectrometry: Radical Chain Reactions,
Angew. Chem. 2002, 114, 15 2863-2866, fulltext
(de); Angew. Chem. Int. Ed. 2002, 41, 15, 2738-2742,
fulltext (engl.).
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Ahlke Hayen, Rainer Koch, Wolfgang Saak, Detlef Haase, Jürgen O.
Metzger, 1,3-Stereoinduction in Radical Reactions: Radical Additions
to Dialkyl 2-Alkyl-4-methyleneglutarates, J. Am. Chem. Soc. 2000,
122, 12458-12468, fulltext.
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A. Hayen, R. Koch, J.O. Metzger, 1,3-Stereoinduction
in Radical Reactions, Angew. Chem. 2000, 112,
2898-2900 Angew. Chem. Int. Ed. 2000, 39,
2758-2761, fulltext.
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K. Schwarzkopf, M. Blumenstein, A. Hayen
and J.O. Metzger, Enantioselectivity of the Transfer of Hydrogen Atoms
to Acyclic Prochiral Carbon-Centred Radicals Using Chiral Tin Hydrides,
Eur. J. Org. Chem. 1998, 177-181, fulltext.
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J.O. Metzger, R. Mahler and G. Francke, Radical Additions
of Alkyl 2-Haloalkanoates and 2-Haloalkanenitriles to Alkenes Initiated
by Electron Transfer from Copper in Solvent-Free Systems, Liebigs
Ann./Recueil 1997, 2303-2313, fulltext.
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K. Schwarzkopf, J.O. Metzger, W. Saak and S. Pohl, Synthesis
of Novel Optical Active Tin Hydrides Containing Chiral Ligands, Chem.
Ber./Recueil 1997, 1539-1546, fulltext.
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M. Blumenstein, K. Schwarzkopf und J.O. Metzger, Enantioselective
Hydrogen Transfer from a Chiral Tin Hydride to a Prochiral Carbon-Centered
Radical , Angew. Chem. 1997, 107, 245-247, fulltext(de);
Angew. Chem. Int. Ed. Engl. 1997, 107, 235-236,
fulltext(engl.).
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J.O. Metzger, Ralf Mahler and Andreas Schmidt, Electron
Transfer Initiated Free Radical Additions of Perfluoroalkyl Iodides
and Diiodides to Alkenes, Liebigs Ann. 1996, 693-696, fulltext.
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J.O. Metzger and Ralf Mahler, Radical Additions of Activated
Haloalkanes to Alkenes Initiated by Electron Transfer from Copper
on Solvent-Free Systems, Angew. Chem. 1995, 107, 1012-1015,
fulltext(de); Angew. Chem. Int. Ed. Engl. 1995, 34,
902-904, fulltext(engl.).

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J.O. Metzger and Fritz Bangert, Ane Additions
to Unsaturated Fatty Compounds: Thermally Initiated Additions of Alkanes
to Methyl 10-Undecenoate, Fat Sci. Technol. 1995, 97,
7-9, fulltext.
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J.O. Metzger, K. Schwarzkopf, W. Saak
and S. Pohl, Stereoselectivity of the Transfer of Hydrogen Atoms to
Cyclic Alkyl Radicals, Chem. Ber. 1994, 127, 1-5,
fulltext.
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J.O. Metzger and F. Bangert, Kinetics
of the Addition of Cyclohexane to Phenylethyne under Supercritical
Fluid Conditions, Chem. Ber. 1994, 127, 1-4,
fulltext.
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J. O. Metzger und M. Blumenstein, Stereoselectivity
of the Thermally Initiated Free-Radical Chain Addition of Cyclohexane
to 1-Alkynes, Chem. Ber., 1993, 126, 2493-2499,
fulltext.
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B. Giese, H. Farshchi, J. Hartmanns und
J.O. Metzger, Isoselective Relationship for the Stereoselectivity
of the Transfer of Hydrogen Atoms to Cyclic Alkyl Radicals, Angew.
Chem., 103 (1991) 619, fulltext(de);
Angew. Chem. Int. Ed. Engl. 30 (1991) 600-601,
fulltext(engl.).
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J.O. Metzger, Addition of Cyclohexane
to 1-Octene in a Free radical Chain Reaction at Supercritical Fluid
Conditions, J. Prakt. Chem., 332, 767 (1990),
fulltext.
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J.O. Metzger und K. Klenke, Investigations
on the Selectivity of the b-Scission of
Alkyl Radicals, II - Selectivity of the b-Fragmentation
of a-(Methoxycarbonyl)alkyl Radicals, Chem.
Ber. 123, 875 (1990), fulltext.
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K. Klenke und J.O. Metzger, The Influence
of Polar and Steric Effects on the Selectivity of the b-Cleavage
of Alkyl Radicals, Angew. Chem. 100, 1195 (1988),
fulltext(de); Angew. Chem. Int. Ed. Engl. 27, 1168 (1988),
fulltext(engl.).
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B. Giese, J.A. Gonzales-Gomez, St. Lachhein
und J.O. Metzger, Influence of H-Donor and Temperature on the Stereoselectivity
of Radical Reactions, Angew. Chem. 99, 475 (1987), fulltext(de);
Angew. Chem. Int. Ed. Engl. 26, 479 (1987), fulltext(engl.).
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D. Malwitz und J.O. Metzger, Thermally
Induced Redox Reaction of Carbonyl Compounds and Alcohols in a Radical
Chain Reaction, Chem. Ber. 119, 3558 (1986),
fulltext.
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D. Malwitz und J.O. Metzger, Thermally
Induced Redox Reaction of Carbonyl Compounds and Alcohols in a Radical
Chain Reaction: Comproportionation to Two Hydroxyalkyl Radicals, Angew.
Chem. 98, 747 (1986), fulltext(de);
Angew. Chem. Int. Ed. Engl. 25, 762 (1986), fulltext(engl.).
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J.O. Metzger, Formation of Alkyl Radicals
by Thermal Bimolecular Reaction of Alkanes and Alkenes, Angew. Chem.
95, 915 (1983), fulltext(de); Angew.
Chem. Int. Ed. Eng. 22, 889 (1983); Angew. Chem. Suppl. 1983,
1256, fulltext(engl.).

Gesamtliste der Publikationen

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